194346-17-3Relevant articles and documents
Regio- and stereoselective addition of trans-Pt(TeAr)(SiMe3)(PEt3)2 to terminal alkynes leading to cis-[(Z)-β-trimethylsilylalkenyl]platinum(II) complexes
Han, Li-Biao,Mirzaei, Farzad,Shimada, Shigeru
, (2018)
Selective insertion of terminal alkynes RC≡CH into the Si—Pt bond of trans-Pt(TeAr)(SiMe3)(PEt3)2 took place readily to produce the corresponding novel alkenyl complexes cis-Pt(TeAr)[(Z)-CR=CHSiMe3](PEt3)2. The structure of the complex was characterized by an X-ray analysis.