19446-68-5Relevant articles and documents
PREPARATIVE UV-LASER PHOTOCHEMISTRY OF THE AZOALKANE SPIRO(2,3-DIAZABICYCLOHEPT-2-ENE-7',1-CYCLOPROPANE): TRAPPING OF THE 1,4-DIRADICAL 2-(3-CYCLOPENTENYL)ETHYL BY MOLECULAR OXYGEN
Adam, Waldemar,Hannemann, Klaus,Hoessel, Peter
, p. 181 - 184 (2007/10/02)
Photo-extrusion of nitrogen from the azoalkane 1 in the presence of molecular oxygen gave besides the hydrocarbons 3 and 5, the endoperoxide 10 and hydroperoxide 11, the former via trapping of the 1,4-diradical 4 by triplet oxygen, the latter by ene-reaction of hydrocarbon 5 with singlet oxygen.