89780-89-2Relevant articles and documents
1,3-Cyclopentanediyls - Intermediates or Transition States?
Roth, Wolfgang R.,Bauer, F.,Breuckmann, Rolf
, p. 2041 - 2046 (2007/10/02)
The energy well of the singlet diradicals 4a and 6 has been determined by the oxygen trapping technique to be 2.7 and 1.9 kcal/mol, respectively.From the oxygen and temperature dependence of the trapping rate of the diradical 4a activation barriers of 2.2 and 4.9 kcal/mol have been derived for the mutual interconversion of the spin isomers with the triplet being the ground state. Key Words: 1,3-Diradicals, energy well, singlet-triplet splitting / 1,3-Cyclopentanediyls
PREPARATIVE UV-LASER PHOTOCHEMISTRY OF THE AZOALKANE SPIRO(2,3-DIAZABICYCLOHEPT-2-ENE-7',1-CYCLOPROPANE): TRAPPING OF THE 1,4-DIRADICAL 2-(3-CYCLOPENTENYL)ETHYL BY MOLECULAR OXYGEN
Adam, Waldemar,Hannemann, Klaus,Hoessel, Peter
, p. 181 - 184 (2007/10/02)
Photo-extrusion of nitrogen from the azoalkane 1 in the presence of molecular oxygen gave besides the hydrocarbons 3 and 5, the endoperoxide 10 and hydroperoxide 11, the former via trapping of the 1,4-diradical 4 by triplet oxygen, the latter by ene-reaction of hydrocarbon 5 with singlet oxygen.