19449-94-6Relevant academic research and scientific papers
Modification of Pathways for Cathodic Reduction via Complexation with β-Cyclodextrin
Smith, Carmen Z.,Utley, James H. P.
, p. 492 - 494 (1981)
Complexation of electroactive substrates with β-cyclodextrin can profoundly alter the course of their reactions; for the cathodic reduction of complexes of ethyl cinnamate, benzaldehyde, and benzophenone protonation of radical-anions is highly efficient whereas a previously unobserved reductive coupling is found for the acetophenone complex.
Electroreductive acylation of activated olefins using a reactive metal anode
Ohno, Toshinobu,Aramaki, Hideo,Nakahiro, Hideki,Nishiguchi, Ikuzo
, p. 1943 - 1952 (2007/10/03)
Electroreductive acylation of 3-aryl substituted α,β-unsaturated esters and nitriles in the presence of aliphatic carboxylic anhydrides using reactive metal anode (Mg, Al, Zn) in an undivided cell afforded the corresponding β-acyl compounds in moderate to good yields. It was found that anionic species formed by electron transfer from a cathode may be stabilized by metal ions freshly formed from an anode and undergo electrophilic attack of carboxylic anhydrides to give the β-acyl products in high yields as compared with the previously reported method using a divided cell.
Electroreductive silylation of activated olefins using a reactive metal anode
Ohno,Nakahiro,Sanemitsu,Hirashima,Nishiguchi
, p. 5515 - 5516 (2007/10/02)
Electroreductive silylation of α, β-unsaturated esters, nitriles and ketones in the presence of Me3SiCl using a reactive metal anode (Mg, Zn, Al) in an undivided cell afforded the corresponding β-silyl compounds offering a valuable method for introduction of a silyl group into activated olefins.
