194672-66-7Relevant academic research and scientific papers
The reactivity of furanoid and pyranoid glycals towards aromatic Grignard reagents and a nickel catalyst
Tingoli, Marco,Panunzi, Barbara,Santacroce, Federico
, p. 9329 - 9332 (1999)
By reaction with aromatic Grignard reagents in the presence of low valent nickel species at low temperature, the 1,2-unsaturated furanoid glycal (1) undergoes coupling reaction to produce 2,3-unsaturated products (1a,b) as pure stereoisomers. When these r
Synthesis of erythro and threo furanoid glycals from 1- and 2-phenylselenenyl-carbohydrate derivatives
Bravo, Fernando,Kassou, Mohamed,Diaz, Yolanda,Castillon, Sergio
, p. 83 - 97 (2007/10/03)
Differently protected erythro and threo furanoid glycals were synthesized by selenoxide elimination when phenyl 1-selenoglycosides were treated in oxidizing conditions (tBuOOH, Ti(OiPr)4, Et2iPrN). Th
Synthesis of erythro and threo furanoid glycals using 5-endo-trig selenoetherification as key step
Bravo,Kassou,Castillon
, p. 1187 - 1190 (2007/10/03)
Differently protected erythro and threo furanoid glycals were synthesised from 4-pentene-1,2,3-triol, through selenium induced 5-endo-trig cyclization and selenoxide elimination.
