1948-04-5Relevant articles and documents
General, practical and selective oxidation protocol for CF3s into CF3S(O) group
Sokolenko, Liubov V.,Orlova, Raisa K.,Filatov, Andrey A.,Yagupolskii, Yurii L.,Magnier, Emmanuel,Pégot, Bruce,Diter, Patrick
, (2019/04/05)
A simple and efficient protocol for the oxidation of trifluoromethyl, mono- and difluoromethyl sulfides to the corresponding sulfoxides without over-oxidation to sulfones, using TFPAA prepared in situ from trifluoroacetic acid and 15% H2O2 aqueous solution was developed. The methodology is suitable for a wide range of aromatic and aliphatic substrates in milligram and multigram scales.