195149-97-4Relevant academic research and scientific papers
Assay for the enantiomeric analysis of [2H1]-fluoroacetic acid: Insight into the stereochemical course of fluorination during fluorometabolite biosynthesis in Streptomyces cattleya
O'Hagan, David,Goss, Rebecca J. M.,Meddour, Abdelkrim,Courtieu, Jacques
, p. 379 - 387 (2003)
A sensitive method for the configurational analysis of (R)- and (S)-[2H1]-fluoroacetate has been developed using 2H{1H}-NMR in a chiral liquid crystalline solvent. This has enabled biosynthetic experiments to be
A short synthesis of (1S,2R)- and (1R,2R)-[1-2H]-glycerols
Nieschalk, Jens,O'Hagan, David
, p. 2325 - 2330 (2007/10/03)
A straightforward three step route to (1S,2R)- and (1R,2R)-[2H]-glycerols 1a and 1b is reported. The key asymmetric step involves an AD-mix-β dihydroxylation on deuterium labelled Z- and E-allyl benzoates 4a and 4b. The route should facilitate
