195192-35-9Relevant academic research and scientific papers
1,2-Diacetals in synthesis: Total synthesis of a glycosylphosphatidylinositol anchor of Trypanosoma brucei
Baeschlin, Daniel K.,Chaperon, Andre R.,Green, Luke G.,Hahn, Michael G.,Ince, Stuart J.,Ley, Steven V.
, p. 172 - 186 (2007/10/03)
A full account on a total synthesis of GPI anchor 1 employing butanediacetal (BDA) groups and a chiral bis(dihydropyran) is presented. The reactivity of selenium and thio glycosides was tuned by the use of BDA groups. This allowed the assembly of an appro
Synthesis of a trisaccharide fragment corresponding to the lipopolysaccharide region of vibrio parahaemolyticus
Van Strafen,Kriek,Timmers,Wigchert,Van Der Marel,Van Boom
, p. 947 - 966 (2007/10/03)
Vicinal syn-dihydroxylation of D-manno-hept-6-enopyranosides 4 and 10 with OsO4 afforded D-glycero-α-D-manno-heptopyranosides 5 and 11, respectively, in good yield and with a high degree of stereoselectivity. Compound 5 was converted into DD-He
