195254-01-4

Upstream product

• 135-02-4 ortho-anisaldehyde 
• 58378-33-9 o-anisaldehyde dimethyl acetal 
• 2862-10-4 benzyl-(2-benzyloxycarbonylamino-2-deoxy-α-D-glucopyranoside) 

Downstream Products

• 195254-07-0 benzyl 3-O-methyl-2-benzyloxycarbonylamino-2-deoxy-4,6-O-(R)-(2-methoxybenzylidene)-α-D-glucopyranoside 
• 195254-04-7 benzyl 3-O-allyl-2-benzyloxycarbonylamino-2-deoxy-4,6-O-(R)-(2-methoxybenzylidene)-α-D-glucopyranoside 

Relevant academic research and scientific papers

Unexpected products in the LiA1H4/AlCl3-reduction of 3-O-substituted and N-benzyloxycarbonyl-protected 4,6-O-[2-methoxybenzylidene]-α-D-glucosamine derivatives

The reductive cleavage of benzyl 2-benzyloxycarbonylamino-2-deoxy-4,6-O-(2-methoxybenzylidene)-α-D- glucopyranoside 2 with LiA1H4-AlCl3 gave the corresponding 4-O-(2-methoxybenzyl) ether along with the 6-O-ether as expected. When, ho