195372-97-5Relevant academic research and scientific papers
Synthesis and characterization of N-benzoyl-DL-α-valinato complexes of palladium(II), platinum(II). Crystal structure of a complex with deprotonated nitrogen coordinating to the palladium(11)
Gong, Yu-Qiu,Cheng, Yao-Feng,Gu, Jian-Ming,Hu, Xiu-Rong
, p. 3743 - 3746 (2008/10/09)
Reactions of MLCl2 (M = Pd(II), Pt(II) ; L = bipy, phen) with Bzval H2 (Bzval H2 = N-benzoylDL-α-valine) in aqueous solution at pH ～9 gave three complexes [Pd(bipy)(Bzval-N,O)] (1), [Pd(phen)(Bzval-N, O)] · H2O(2) and [Pt(bipy)(Bzval-N,O)] -H2O(3). All of these complexes were characterized by elemental analysis and IR spectra. The structure of 1 has been determined by X-ray diffraction analysis. In all complexes an N-benzoyl-DL-α-valinate dianion coordinates to the metal ion through a deprotonated amide nitrogen and a carboxylic oxygen. There is some intramolecular interaction between phenyl ring and bipy in the complex.
