195388-47-7

Upstream product

• 447-53-0 1,2-Dihydronaphthalene 

Downstream Products

• 936330-65-3 (S)-1-tert-butyldiphenylsiloxy-3,4-dihydro-naphthalene 
• 1313594-45-4 (S)-4-hydroxy-4-phenylnaphthalen-1(4H)-one 
• 1313594-44-3 (S)-4-phenyl-1,2-dihydronaphthalen-1-ol 
• 1313594-43-2 (S)-tert-butyldiphenyl(4-phenyl-1,2-dihydronaphthalen-1-yloxy)silane 
• 1313594-42-1 (S)-(4-bromo-1,2-dihydronaphthalen-1-yloxy)(tert-butyl)diphenylsilane 
• 885122-07-6 (1S,3S)-1-tert-butyldiphenylsiloxy-3-hydroxy-3-isopropenyl-1,2,3,4-tetrahydro-naphthalen-3-one 
• 885122-10-1 (S)-1-tert-butyldiphenylsiloxy-3-hydroxy-1,2,3,4-tetrahydro-naphthalen-3-one 
• 936330-66-4 (1S)-1-tert-butyldiphenylsiloxy-3-hydroxy-1,2,3,4-tetrahydro-naphthalene 
• 936330-68-6 (1S,3S)-1-tert-butyldiphenylsiloxy-3-acetyl-3-hydroxy-1,2,3,4-tetrahydro-naphthalene 

Relevant academic research and scientific papers

Asymmetric Hydroxylation, Epoxidation and Sulfoxidation Catalyzed by Vaulted Binaphthyl Metalloporphyrins

A chiral, vaulted binaphthyl porphyrin (1) has been prepared from 5α,10β,15α,20β-tetrakis(o-aminophenyl)porphyrin and (R)-(+)-2,2'-dimethoxy-1,1'-bi-6-naphthoyl chloride in 79 percent yield.Asymmetric oxygenations of alkanes, alkenes, and alkyl sulfides were catalyzed with the chloroiron(III) and chloromanganese(III) complexes of 1 with good yields and high stereoselectivities.The first catalytic asymmetric hydroxylations are reported for 1-Fe(III)Cl with enantiomeric excesses in the range of 40-72 percent.The corresponding manganese catalyst, 1-Mn(III)Cl, gave much lower enantiomeric excesses.For catalytic asymmetric epoxidations, enantiomeric excesses were in the range of 20-72 percent.Prochiral alkyl sulfides gave sulfoxides with 14-48 percent ee with 1-Fe(III)Cl.