195391-98-1Relevant articles and documents
Reductive diallylation of natural amino acids with triallylborane. The first synthesis of chiral 1,1-diallyl-2-amino alcohols and their cyclization into optically active pyrrolidines
Bubnov, Yuri N.,Misharin, Mikhail A.,Ignatenko, Anatoly V.
, p. 6259 - 6262 (1997)
The titled amino alcohols are obtained by treatment of chiral amino acids with triallylborane. Electrophylic iodocyclization of the alcohols leads to pyrrolidine derivatives.
Diethylzinc: A simple and efficient catalyst for the swift hydroamination at room temperature
Pissarek, Jens-Wolfgang,Schlesiger, David,Roesky, Peter W.,Blechert, Siegfried
supporting information; experimental part, p. 2081 - 2085 (2009/12/28)
Diethylzinc and dimethylanilinium tetrakis(pentafluorophenyl)borate were found to catalyze hydroaminations at room temperature in high efficiency and very short reaction times. The reactivity of the proposed cationic zinc species, which is assumed to cata