195436-27-2

Upstream product

• 2878-55-9 3,4-(methylenedioxy)benzyl α-ethoxyethyl ether 
• 100-39-0 benzyl bromide 
• 160094-76-8 4-hydroxy-5-(1-ethoxyethyl)oxymethyl-1,3-benzodioxolane 

Downstream Products

• 195436-19-2 [(3aS,4S,7R,7aS)-7-(4-Benzyloxy-benzo[1,3]dioxol-5-ylmethoxy)-2,2-dimethyl-3a,4,7,7a-tetrahydro-benzo[1,3]dioxol-4-yloxy]-tert-butyl-dimethyl-silane 
• 168610-72-8 (3aR,4S,7R,7aS)-7-(4-Benzyloxy-benzo[1,3]dioxol-5-ylmethoxy)-2,2-dimethyl-3a,4,7,7a-tetrahydro-benzo[1,3]dioxol-4-ol 
• 160094-77-9 4-phenylmethoxy-5-hydroxymethyl-1,3-benzodioxolane 

Relevant academic research and scientific papers

A novel case of cationic rearrangement involving a phenonium ion

A cationic rearrangement was observed in the intramolecular electrophilic substitution of a trioxygenated benzyl ether. The crystal structure of the product is presented

A convergent synthesis of (+)-pancratistatin based on intramolecular electrophilic aromatic substitution

A convergent formal synthesis of (+)-pancratistatin (1) is reported. Specifically, an optically active adduct of piperonyl bromide and acetonated conduritol A was converted to a late-stage intermediate from the Danishefsky-Lee synthesis of 1. The carbon s