19551-16-7Relevant academic research and scientific papers
Synthesis, characterization and application of poly(N,N'-dibromo- Nethylnaphthyl-2,7-disulfonamide) as an efficient catalyst for the acetylation and deacetylation reactions
Khazaei, Ardeshir,Saednia, Shahnaz,Roshani, Liela,Kazem-Rostami, Masoud,Zare, Abdolkarim
, p. 159 - 167 (2014/05/20)
In this work, a novel polymer namely poly(N,N'-dibromo-N-ethylnaphthyl-2,7- disulfonamide) (PBNS) is synthesized and characterized by studying its IR, 1H NMR, 13C NMR and thermal gravimetric analysis (TGA). This polymer is utilized as a highly efficient, heterogeneous and recyclable N-bromo reagent to catalyze acetylation of various compounds such as alcohols, phenols, thiol and amine with acetic anhydride under solvent-free conditions, and also it worthily catalyzes deacetylation of acetate esters in aqueous media.
ACYLSULFONAMIDES AND PROCESSES FOR PRODUCING THE SAME
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Page/Page column 95; 96, (2012/03/09)
The present disclosure relates to acylsulfonamides and processes for their preparation. The processes involve a target-guided synthesis approach, whereby a thioacid and a sulfonyl azide are reacted in the presence of a biological target protein, a Bcl-2 family protein, to form the acylsulfonamide.
Dependence of single-molecule conductance on molecule junction symmetry
Taniguchi, Masateru,Tsutsui, Makusu,Mogi, Ryoji,Sugawara, Tadashi,Tsuji, Yuta,Yoshizawa, Kazunari,Kawai, Tomoji
supporting information; scheme or table, p. 11426 - 11429 (2011/10/04)
The symmetry of a molecule junction has been shown to play a significant role in determining the conductance of the molecule, but the details of how conductance changes with symmetry have heretofore been unknown. Herein, we investigate a naphthalenedithiol single-molecule system in which sulfur atoms from the molecule are anchored to two facing gold electrodes. In the studied system, the highest single-molecule conductance, for a molecule junction of 1,4-symmetry, is 110 times larger than the lowest single-molecule conductance, for a molecule junction of 2,7-symmetry. We demonstrate clearly that the measured dependence of molecule junction symmetry for single-molecule junctions agrees with theoretical predictions.
SYNTHESIS AND SOME TRANSFORMATIONS OF (2,7-NAPHTHYLENEDITHIO)- AND (2,6-NAPHTHYLENEDITHIO)DIACETIC ACID
Lisitsyn, V. N.,Kukalenko, L. S.,T-sat-sakis, A. M.
, p. 145 - 148 (2007/10/02)
(2,7-Naphthylenedithio)- and (2,6-naphthylenedithio)diacetic acids were obtained from 2,7- and 2,6-naphthalenedisulfonic acids respectively and were oxidized to (2,7-naphthylenedisulfonyl)diacetic acids with hydrogen peroxide in acetic acid.The nitration of (2,6-naphthylenedithio)diacetic acid leads to the formation of (1,5-dinitro-2,6-naphthylenedithio)diacetic acid.
