195827-82-8

Usage

InChI:InChI=1/C35H38O6/c1-36-35-34(40-25-30-20-12-5-13-21-30)33(39-24-29-18-10-4-11-19-29)32(38-23-28-16-8-3-9-17-28)31(41-35)26-37-22-27-14-6-2-7-15-27/h2-21,31-35H,22-26H2,1H3/t31-,32+,33+,34-,35-/m1/s1

Upstream product

• 97-30-3 methyl D-galactopyranoside 
• 100-39-0 benzyl bromide 
• 4291-68-3 (2R,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-chloro-tetrahydro-pyran 
• 1391849-30-1 (2S,3S,4R)-2-azido-3,4-O-isopropyliden-6-oxa-1,3,4-nonanetriol 
• 3396-99-4 methyl α-D-galactopyranoside 

Downstream Products

• 61277-56-3 1,6-di-O-acetyl-2,3,4-tri-O-benzyl-α/β-D-galactopyranose 
• 82598-84-3 2,3,4,6-tetra-O-benzyl-D-galactonolactone 
• 4132-28-9 2,3,4,6-tetra-O-benzyl-α-D-galactopyranose 
• 4132-28-9 2,3,4,6-tetra-O-benzyl-D-galactopyranose 
• 6386-24-9 2,3,4,6-tetra-O-benzyl-D-galactopyranose 

Relevant academic research and scientific papers

Highly (Z)-Diastereoselective Synthesis of Trifluoromethylated exo-Glycals via Photoredox and Copper Catalysis

Highly (Z)-diastereoselective approaches for the synthesis of trifluoromethylated exo-glycals by copper and photoredox catalysis are described. These complementary reactions are applicable to a wide range of methylene exo-glycals generated from the corresponding pyranoses and furanoses and give trifluoromethylated compounds under mild conditions in moderate to good yields. DFT calculations have allowed a rationalization of the observed (Z)-stereoselectivity.

Gold-catalysed glycosylation reaction using an easily accessible leaving group

Gold(iii)-catalysed glycosylation reaction has been developed by employing a new and easily accessible leaving group synthesized from ethyl cyanoacetate. Several nucleophiles like alcohols, thiols, allyltrimethylsilane, trimethylsilyl azide and triethylsilane have been reacted to make the corresponding glycosides in good yields and with marginal to excellent α-selectivity. This journal is

Synthesis and biological evaluation of truncated α-galactosylceramide derivatives focusing on cytokine induction profile

A series of truncated analogs of α-galactosylceramide with altered ceramide moiety was prepared, and evaluated for Th2-biased response in the context of IL-4/IFN-γ ratio. Phytosphingosine-modified analogs including cyclic, aromatic and ethereal compounds

X-ray crystal structure determinations of galactosylacetylene building blocks

We report the crystal structures of two galactosylacetylenes: 3,7-anhydro-4,5,6,8-tetra-O-benzyl-1,1,2,2-tetradehydro-1,2-dideoxy-1-C- (trimethylsilyl)-D-glycero-L-mann ooctitol (7) and 3,7-anhydro-4,5,6,8-tetra-O- benzyl-1,1,2,2-tetradehydro-1,2-D-glycero-L-mannooctitol (8). A short overview of the synthetic chemistry used to obtain these targets is mentioned. Copyright Taylor & Francis Group, LLC.

Synthesis of an artificial glycoconjugate polymer carrying P(k)-antigenic trisaccharide and its potent neutralization activity against Shiga-like toxin

Fluorescence-labeled glycoconjugate polymers carrying carbohydrate segments of a globotriaosyl ceramide (Gb3) were synthesized and subjected to biological assays using Escherichia coli O-157 strains and Shiga-like toxins (Stx-I and Stx-II). For