19592-09-7Relevant academic research and scientific papers
Electrochemical One-electron Oxidation of 5>2-: Spectroscopic and Magnetic Evidence for the (t2g5) Ruthenium(III) Pentachloronitrosyl Complex Monoanion 5>-
Coombe, Vyvyan T.,Heath, Graham A.,Stephenson, T. Anthony,Tocher, Derek A.
, p. 303 - 304 (1983)
Voltammetric measurements establish a reversible one-electron oxidation for2- in CH2Cl2; the i.r. and e.s.r. spectra and magnetic properties of the electrogenerated deep green product are consistent with low-spin -, and quite different from the properties recently attributed to this anion.
Chloro complexes of nitrosylruthenium
Mercer,Campbell Jr.,Wallace
, p. 1018 - 1024 (1964)
An investigation of the nitrosylruthenium chloro complexes formed in hydrochloric acid solutions has shown the existence of five monomeric complexes. The mono-, di-, tri-, tetra-, and pentachloro complexes were isolated by ion exchange and were shown to have the formulas RuNOCl(H2O)4+2, RuNOCl2(H2O)3+, RuNOCl3(H2O)2, RuNOCl4(H2O)-, and RuNOCl5-2 in acid media. The complex RuNOCl4(H2O)- is a weak acid that dissociates to produce RuNOCl4(OH)-2 with a dissociation constant of 9.5 × 10-7. RuNOCl3(H2O)2 is a weak dibasic acid that dissociates to produce RuNOCl3(H2O)(OH)-and RuNOCl3(OH)2-2 with successive dissociation constants of 1.1 × 10-5 and 3.4 × 10-8. One other chloro complex was detected but was not characterized.
