1960-46-9Relevant academic research and scientific papers
A METHOD TO PRODUCE BORANE COMPLEXES, REAGENTS FOR THE SAME, AND USE OF THE REAGENTS
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Page/Page column 11; 23-24, (2017/11/06)
The present invention relates to a diborane-free method for producing borane complexes, such as borane dimethyl sulfide. The method includes reacting boron trifluoride and a Lewis base with a certain tertiary amines, such as 1,2,2,6,6- pentamethylpiperidineunder hydrogen atmosphere. The invention relates also to recovery of side products produced, and reagents for use in preparation of borane complexes.
Dehydrofluorination of amine-metalloid fluorides. III. The dehydrofluorination of primary amine-boron trifluoride adducts
Harris, James J.,Rudner
, p. 1258 - 1262 (2008/10/08)
Primary amine adducts of boron trifluoride or salts of fluoroboric acid are readily dehydrofluorinated by the adducts of hindered, preferably tertiary amines with boron trifluoride. The procedure has been applied primarily to the preparation of B-fluorobo
