19604-61-6Relevant academic research and scientific papers
SOLVOLYTIC HYDROPEROXIDE REARRANGEMENTS IV. Selective Rearrangement of Spirooctan-4-ol.
Ronald, Robert C.,Ruder, Suzanne M.,Lillie, Thomas S.
, p. 131 - 134 (2007/10/02)
Rearrangement of spirooctan-4-ol, 1, in acidified THF-H2O2 is a selective process in which substitution occurs with retention of configuration and ring-expansion with inversion of the carbinyl center.
NOVEL CARBON-CARBON BOND CLEAVAGE REACTIONS OF α-AZOHYDROPEROXIDES
Utaka, Masanori,Fujita, Yuji,Takeda, Akira
, p. 1607 - 1610 (2007/10/02)
1-Phenylazo-1-hydroperoxycyclohexanes, easily prepared by the autoxidation of cyclohexanone phenyl hydrazones, have been found to undergo C(1)-C(2) bond cleavages when treated with acids, bases, or reducing reagents under mild conditions.Thus 6-oxoalkanoic acids and their derivatives have been obtained in good yields from 2-hydroxycyclohexanone derivatives.The 2-hydroxyl group seems to play an important role for the cleavage.
