196085-29-7Relevant academic research and scientific papers
Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling
Fan, Lulu,Jia, Jiaqi,Hou, Hong,Lefebvre, Quentin,Rueping, Magnus
, p. 16437 - 16440 (2016)
A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C?O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.
Zirconium-mediated intramolecular coupling reactions of unsaturated anilines. Diastereoselective synthesis of azetidines
Barluenga, Jose,Sanz, Roberto,Fananas, Francisco J.
, p. 5953 - 5958 (2007/10/03)
Imine complexes of zirconocene, generated by a β-hydrogen abstraction process, which possess a carbon-carbon multiple bond, undergo inter- or intramolecular carbometalation to afford 1,4-cyclohexanediamine or cycloalkylaniline derivatives depending on the relative position of the unsaturated moiety with respect to the imine complex. A new diastereoselective synthesis of azetidines has been developed by treatment of azazirconacyclopentanes with iodine.
