1961-93-9

Upstream product

• 276-32-4 Bicyclo<6.3.0>undeca-1,3,5,8,10-pentaen 
• 30463-06-0 1,1-dibromo-2-<(E)-2-phenyl-1-ethenyl>cyclopropane 
• 56667-10-8 (RS)-1-phenylcyclopent-2-en-1-ol 12 
• 65754-71-4 bicyclo<5.3.1>undeca-1,3,5,7,9-pentaene 
• 930-30-3 cyclopent-2-enone 
• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 1840-42-2 fluorotrinitromethane 
• 100-59-4 phenylmagnesium chloride 
• 108-86-1 bromobenzene 

Downstream Products

• 122123-21-1 bis(η5-phenylcyclopentadienyl)dichlorozirconium (IV) 

Relevant academic research and scientific papers

Zirconocene-catalyzed dimerization of 1-hexene: Two-stage activation and structure-catalytic performance relationship

The dimerization of 1-hexene was catalyzed by ten zirconocenes. High catalytic productivity was achieved via a two-step activation process, namely, the treatment of the zirconocene with triisobutylaluminum (TIBA) followed by methylaluminoxane (MAO). The z

Formation and synthetic utility of benzyl- and phenyl-cyclopentadienylthallium

Benzyl- and phenyl-cyclopentadiene have been shown to react with thallium ethoxide in ethanol to give the corresponding benzyl- and phenyl-cyclopentadienylthallium compounds in excellent yield.These reagents are air stable for brief periods, have extended shelf-lives, and have been shown to be superior starting materials for the synthesis of a variety of cyclopentadienylmetal complexes.

Chemistry of gem-Dihalocyclopropanes. XX. The Effect of Methyl and Phenyl Substituents on the Vinylcyclopropylidene-Cyclopentenylidene Rearrangement

Reactions of gem-dibromocyclopropanes of the general structure 1 with methyllithium have been studied.In the most cases cyclopentadienes and/or vinylallenes are the products formed.The results obtained give evidence of a profound substituent effect on the carbene-carbene rearrangement leading to cyclopentadienes.We believe the effect is essentially steric in origin.The results support the mechanism proposed for the rearrangement.