196106-76-0Relevant academic research and scientific papers
Stereospecific access to trisubstituted enol ethers from vinylsilanes
Barluenga, Jose,Alvarez-Garcia, Lorenzo J.,Romanelli, Gustavo P.,Gonzalez, Jose M.
, p. 6763 - 6766 (1997)
The reaction of RCH=CHSiMe3 (R: alkyl or aryl) with IPy2BF4/HBF4 and a set of representative alcohols affords the corresponding addition products as a single regio- and stereoisomers in good yield. Subsequent dehydroiodination with DBU furnishes silyl-substituted enol ethers.
