
Tetrahedron Letters p. 6763 - 6766 (1997)
Update date:2022-07-30
Topics:
Barluenga, Jose
Alvarez-Garcia, Lorenzo J.
Romanelli, Gustavo P.
Gonzalez, Jose M.
The reaction of RCH=CHSiMe3 (R: alkyl or aryl) with IPy2BF4/HBF4 and a set of representative alcohols affords the corresponding addition products as a single regio- and stereoisomers in good yield. Subsequent dehydroiodination with DBU furnishes silyl-substituted enol ethers.
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(1968)