196212-80-3

Basic information

• Product Name: 2-((S)-1-Phenyl-ethyl)-benzo[1,3,2]dioxaborole
• Synonyms: 2-((S)-1-Phenyl-ethyl)-benzo[1,3,2]dioxaborole
• CAS NO: 196212-80-3
• Molecular Weight: 224.067
• Mol File: 196212-80-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-((S)-1-Phenyl-ethyl)-benzo[1,3,2]dioxaborole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((S)-1-Phenyl-ethyl)-benzo[1,3,2]dioxaborole(196212-80-3)
• EPA Substance Registry System: 2-((S)-1-Phenyl-ethyl)-benzo[1,3,2]dioxaborole(196212-80-3)

Safety Data

• Hazardous Substances Data: 196212-80-3(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 13826-27-2 2,2'-bis(1,3,2-benzodioxaborole) 
• 274-07-7 benzo[1,3,2]dioxaborole 

Downstream Products

• 1445-91-6 (S)-1-phenylethanol 
• 1517-69-7 (R)-1-phenylethanol 
• 59850-51-0 (2R,3S)-2-amino-3-phenyl-butyric acid hydrochloride 
• 505094-50-8 1,1-dimethylethyl N-(diphenylmethylene)-(βS)-methyl-D-phenylalaninate 
• 505094-48-4 1,1-dimethylethyl N-(diphenylmethylene)-(βR)-methyl-D-phenylalaninate 
• 505094-49-5 1,1-dimethylethyl N-(diphenylmethylene)-(βS)-methyl-L-phenylalaninate 
• 505094-47-3 1,1-dimethylethyl N-(diphenylmethylene)-(βR)-methyl-L-phenylalaninate 
• 505094-36-0 9-((S)-1-Phenyl-ethyl)-9-bora-bicyclo[3.3.1]nonane 
• 59850-51-0 threo-(+)-(2S,3R)-L-β-Methylphenylalanine hydrochloride 
• 53331-55-8 (2S,3S)-β-methylphenylalanine hydrochloride 
• 59850-51-0 (2R,3R)-2-acetylamino-3-methyl-3-phenylalanine hydrochloride 

Relevant articles and documents

Rh(I)-catalyzed asymmetric hydrosilylation and hydroboration/oxidation reactions using berens ligand

The Berens ligand 2 was used in a number of Rh(I)-catalyzed asymmetric hydrosilylations of acetophenones under standard conditions, affording the corresponding 1-arylalcohols in ees up to 65%. Some novel Rh catalysts were generated in situ from the neutral precatalyst [Rh(μ-Cl)(COD)]2 and screened in the catalytic asymmetric hydroboration/oxidation of styrenes, gave enantioselectivities of up to 62%. Copyright Taylor & Francis Group, LLC.

Acyclic stereoselective boron alkylation reactions for the asymmetric synthesis of β-substituted α-amino acid derivatives

Optically active syn- or anti-β-substituted-α-amino acid derivatives are prepared in 94 to ≥99% ee and 66-98% ds by reaction of the Schiff base acetate of glycine tert-butyl ester with chiral, nonracemic B-alkyl-9-BBN derivatives in the presence of the Cinchona alkaloid, cinchonidine (CdOH) or cinchonine (CnOH), base, and lithium chloride. Copyright