19635-58-6Relevant academic research and scientific papers
Organometallic compounds with metal-metal bonds. XV. Synthesis and infrared spectra of mono(tetracarbonylcobalt) derivatives of tin, tetrakis(tetracarbonylcobalt)tin(IV), and related compounds
Patmore,Graham
, p. 771 - 776 (1968)
The syntheses and infrared spectra of a series of mono(tetracarbonylcobalt)tin(IV) derivatives of the general formula RnX3_nSnCo(CO)4 [R = C6H5; X = Cl, Br, I; n = 0, 1, 2] are reported. Several triphenylphosphine complexes are also described. Assignments are suggested for the carbonyl stretching bands. Cobalt carbonyl reacts with tin(II) fluoride to form FSn-[Co(CO)4]3 and with tin(II) acetate to yield (CH3CO2)2Sn[Co(CO)4]2 and (CH3CO2)Sn[Co(CO)4]3. The preparation of Sn-[Co(CO)4]4 is also reported.
