Organometallic compounds with metal-metal bonds. XV. Synthesis and infrared spectra of mono(tetracarbonylcobalt) derivatives of tin, tetrakis(tetracarbonylcobalt)tin(IV), and related compounds

DOI: 10.1021/ic50062a031

Source and publish data:

Inorganic Chemistry p. 771 - 776 (1968)

Update date:2022-08-04

Topics:

Authors:

Patmore Patmore

Graham Graham

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ic50062a031

The syntheses and infrared spectra of a series of mono(tetracarbonylcobalt)tin(IV) derivatives of the general formula R_nX_{3_n}SnCo(CO)₄ [R = C₆H₅; X = Cl, Br, I; n = 0, 1, 2] are reported. Several triphenylphosphine complexes are also described. Assignments are suggested for the carbonyl stretching bands. Cobalt carbonyl reacts with tin(II) fluoride to form FSn-[Co(CO)₄]₃ and with tin(II) acetate to yield (CH₃CO₂)₂Sn[Co(CO)₄]₂ and (CH₃CO₂)Sn[Co(CO)₄]₃. The preparation of Sn-[Co(CO)₄]₄ is also reported.

Full text of DOI:10.1021/ic50062a031

Products guided by the article

Product name:Cl₂(C₄H₉)SnCo(CO)3P(C₆H₅)3

Cas No:19635-58-6

R&D Labs maybe for 19635-58-6

Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
Anqing World Chemical Co., Ltd.

Contact:+86-556-5800026

Address:Daguan Economic Development Zone of circular economy industrial park Anqing City Anhui province
Zhejiang Chemicals Import & Export Corporation (ZHECHEM)

Contact:+86-571-87046953

Address:No. 37, Qingchun Road
Zibo Ocean International Trade Co.,Ltd(expird)

Contact:+86 533 5160706

Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China

Relevant to this article

The synthesis of enantiopure ω-methanoprolines and ω-methanopipecolic acids by a novel cyclopropanation reaction: The "flattening" of proline

Doi:10.1002/anie.199718811
(1997)
The preparation and intra- and intermolecular addition reactions of acyclic N-acylimines: Application to the synthesis of (±)-sertraline

Doi:10.1021/jo010370l
(2001)
Novel and specific respiratory syncytial virus inhibitors that target virus fusion [3]

Doi:10.1021/jm980239e
(1998)
Synthesis and evaluation of eight aminodeoxy trisaccharide inhibitors for N-acetylglucosaminyltransferase-V

Doi:10.1016/S0008-6215(97)00174-2
(1997)
Phosphido-bridged dimolybdenum complexes with sulfide and thiolate ligands as precursors to mixed-metal clusters

Doi:10.1016/S0022-328X(97)00297-0
(1997)
Potent fluoromethyl ketone inhibitors of recombinant human calpain I

Doi:10.1016/0960-894X(96)00209-0
(1996)

Article Doi