19646-62-9

Upstream product

• 15226-74-1 dicobalt octacarbonyl 
• 1135-99-5 diphenyltin(IV) dichloride 

Downstream Products

• 15020-83-4 (C₆H₅)2Sn{Mn(CO)5}{Co(CO)4} 
• 20298-27-5 I(C₆H₅)2SnCo(CO)4 

Relevant academic research and scientific papers

Organometallic compounds with metal-metal bonds. XV. Synthesis and infrared spectra of mono(tetracarbonylcobalt) derivatives of tin, tetrakis(tetracarbonylcobalt)tin(IV), and related compounds

The syntheses and infrared spectra of a series of mono(tetracarbonylcobalt)tin(IV) derivatives of the general formula RnX3_nSnCo(CO)4 [R = C6H5; X = Cl, Br, I; n = 0, 1, 2] are reported. Several triphenylphosphine complexes are also described. Assignments are suggested for the carbonyl stretching bands. Cobalt carbonyl reacts with tin(II) fluoride to form FSn-[Co(CO)4]3 and with tin(II) acetate to yield (CH3CO2)2Sn[Co(CO)4]2 and (CH3CO2)Sn[Co(CO)4]3. The preparation of Sn-[Co(CO)4]4 is also reported.