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Manganese(II) hexafluoroacetylacetonate, with the molecular formula Mn(C5HF6O2)2, is a deep purple, crystalline solid that plays a significant role in the field of organic chemistry and materials science. It is a versatile catalyst in various organic synthetic reactions and serves as a precursor for the synthesis of other manganese-containing compounds and materials. However, it is considered a hazardous substance that requires careful handling to prevent irritation to the skin, eyes, and respiratory system.

19648-86-3

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19648-86-3 Usage

Uses

Used in Organic Synthesis:
Manganese(II) hexafluoroacetylacetonate is used as a catalyst in organic synthesis for its ability to facilitate various chemical reactions. Its catalytic properties make it a valuable component in the synthesis of complex organic molecules and compounds.
Used in Catalyst Industry:
In the catalyst industry, Manganese(II) hexafluoroacetylacetonate is used as a catalyst precursor for the production of other manganese-containing catalysts. These catalysts are essential in various chemical processes, including the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Materials Science:
Manganese(II) hexafluoroacetylacetonate is also used in materials science as a precursor for the synthesis of manganese-containing materials. These materials have potential applications in various fields, such as energy storage, catalysis, and electronic devices, due to their unique properties and functionalities.
Used in Research and Development:
In the research and development sector, Manganese(II) hexafluoroacetylacetonate is utilized for studying its catalytic properties and exploring its potential applications in new chemical reactions and processes. This helps in advancing the understanding of organic chemistry and materials science, leading to the development of innovative products and technologies.

Check Digit Verification of cas no

The CAS Registry Mumber 19648-86-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,9,6,4 and 8 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 19648-86:
(7*1)+(6*9)+(5*6)+(4*4)+(3*8)+(2*8)+(1*6)=153
153 % 10 = 3
So 19648-86-3 is a valid CAS Registry Number.
InChI:InChI=1/2C5H2F6O2.Mn/c2*6-4(7,8)2(12)1-3(13)5(9,10)11;/h2*1,12H;/q;;+2/p-2/b2-1+;2-1-;

19648-86-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name MANGANESE(II) HEXAFLUOROACETYLACETONATE

1.2 Other means of identification

Product number -
Other names MANGANESE HEXAFLUOROACETYLACETONATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:19648-86-3 SDS

19648-86-3Relevant academic research and scientific papers

Molecular Engineering of MnII Diamine Diketonate Precursors for the Vapor Deposition of Manganese Oxide Nanostructures

Maccato, Chiara,Bigiani, Lorenzo,Carraro, Giorgio,Gasparotto, Alberto,Seraglia, Roberta,Kim, Jiyeon,Devi, Anjana,Tabacchi, Gloria,Fois, Ettore,Pace, Giuseppe,Di Noto, Vito,Barreca, Davide

, p. 17954 - 17963 (2017)

Molecular engineering of manganese(II) diamine diketonate precursors is a key issue for their use in the vapor deposition of manganese oxide materials. Herein, two closely related β-diketonate diamine MnII adducts with different fluorine contents in the diketonate ligands are examined. The target compounds were synthesized by a simple procedure and, for the first time, thoroughly characterized by a joint experimental–theoretical approach, to understand the influence of the ligand on their structures, electronic properties, thermal behavior, and reactivity. The target compounds are monomeric and exhibit a pseudo-octahedral coordination of the MnII centers, with differences in their structure and fragmentation processes related to the ligand nature. Both complexes can be readily vaporized without premature side decompositions, a favorable feature for their use as precursors for chemical vapor deposition (CVD) or atomic layer deposition applications. Preliminary CVD experiments at moderate growth temperatures enabled the fabrication of high-purity, single-phase Mn3O4 nanosystems with tailored morphology, which hold great promise for various technological applications.

Synthesis, structure, and magnetic property of manganese(II) complex of 1,2-closo-carboranyl biradical with S = 3/2 ground state

Iwahori, Fumiyasu,Matsumura, Kazunari,Yamashita, Masahiro,Abe, Jiro

, p. 68 - 69 (2006)

Three-spin magnetic cluster consists of manganese(II) and ortho-carboranyl biradical OCB-BNN have been synthesized and characterized as the first example of the carborane containing paramagnetic complex. The crystal structure of discrete 1:1 complex Mn(hf

(-)-2-(4'-pyridyl)-4,5-pinene-pyridine manganese hexafluoroacetylacetonate complex and preparation method

-

Paragraph 0019; 0021, (2019/01/14)

The invention discloses a (-)-2-(4'-pyridyl)-4,5-pinene-pyridine manganese hexafluoroacetylacetonate complex and a preparation method. A molecular formula is Mn(hfac)2(L)2. The preparation method includes steps: dissolving hexafluoroacetylacetone into methyl alcohol, stirring for 15-20min, adding methyl alcohol while slowly stirring, dropwise adding aqueous solution of MnCl2 4H2O to generate precipitate immediately, filtering, and subjecting the precipitate to washing and vacuum drying to obtain Mn(hfac)2 2H2O; adding Mn(hfac)2 2H2O dissolved n-heptane solution into chiral single-toothed N-containing organic ligand L dissolved dichloromethane solution, continuously stirring for 10-20min, filtering, standing for volatilization to obtain faint yellow crystal after two days, and performing filtering, washing and vacuum drying to obtain the target complex. The mononuclear manganese complex is high in chiral optical activity.

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