19672-38-9Relevant academic research and scientific papers
ALKYLATION OF β-DIKETONES THROUGH THEIR Co(II), Co(III) AND Zn(II) COMPLEXES. 1-BROMOADAMANTANE AS ALKYLATING AGENT.
Gonzalez, A.,Gueell, F.,Marquet, J.,Moreno-Manas, M.
, p. 3735 - 3738 (1985)
α-(1-Adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane.The intermediacy of adamantyl cation is proposed.Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones.
