Tetrahedron Letters p. 3735 - 3738 (1985)
Update date:2022-09-26
Topics:
Gonzalez, A.
Gueell, F.
Marquet, J.
Moreno-Manas, M.
α-(1-Adamantyl)-β-diketones are now accessible by the alkylation of Co(II) complexes of β-diketones with 1-bromoadamantane.The intermediacy of adamantyl cation is proposed.Co(II), Co(III) and Zn(II) complexes of pentane-2,4-dione react with alkyl halides precursors of stabilized carbenium ions, to give 3-alkylpentane-2,4-diones.
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