196795-54-7Relevant academic research and scientific papers
A new and general route to N-unsubstituted azomethine ylides from N-(silylmethyl)thioureas: Cycloaddition of synthetic equivalents of nonstabilized aminonitrile ylides
Tsuge, Otohiko,Hatta, Taizo,Kakura, Yoshikazu,Tashiro, Hideki,Maeda, Hironori,Kakehi, Akikazu
, p. 945 - 946 (1997)
The S-methylation of N-(silylmethyl)thioureas followed by the desilylation generates N-unsubstituted azomethine ylides having both methylthio and amino groups at the ylide carbon. These azomethine ylides react with electron-deficient olefins to give forma
