196859-69-5Relevant academic research and scientific papers
Synthesis of ether linked pseudo-oligosaccharides via 5,6-cyclic sulfate derivatives of protected manno and glucofuranose
Gourlain, Thierry,Wadouachi, Anne,Uzan,Beaupere
, p. 1089 - 1100 (2007/10/03)
C-6 ring opening of 5,6-cyclic sulfate derivatives of protected manno and glucofuranose with carbohydrate alkoxides gave ether linked pseudo-di or trisaccharides. Use of methyl 2,3-O-isopropylidene-5,6-O-sulfuryl-α-D-mannofuranoside 1 led to protected pseudo-disaccharide D-Glcf-(3→6)-D-Manf-(5→6)-D-Manf4 and protected pseudo-trisaccharide D-Manf-(6→3)-D-Glcf-(6→3)-D-Glcf 11 derivatives in 66% and 41% overall yields, respectively.
