197171-53-2Relevant academic research and scientific papers
Synthesis and structure of a five-coordinate organochromium(III) thiolate complex from a chromium(II) alkyl precursor
Fryzuk, Michael D.,Leznoff, Daniel B.,Rettig, Steven J.
, p. 5116 - 5119 (1997)
The reaction of the Cr(II) methyl complex, CrMe[N(SiMe2CH2PPh2)2], with diphenyl disulfide (Ph-SSPh) leads to the formation of the five-coordinate, paramagnetic complex CrMe(SPh)[N(SiMe2CH2PPh2)2] by an overall one-electron oxidation. The complex is unusual in that the phenyl thiolate moiety is terminal and does not engage in bridging to generate a dinuclear system having octahedral Cr(III) centers. The complex was characterized both in solution and in the solid state.
