1973-36-0Relevant articles and documents
Mixed hydride reduction of steroidal diastereomeric oxathiolanes
Shafiullah,Ali, H.,Ogura, H.,Takayanagi, H.
, p. 112 - 116 (2007/10/02)
Mixed hydride reduction of diastereomeric steroidal oxathiolanes such as (6S)-6,6-oxyethylenethio-5α-cholestane 1 and (6R)-6,6-oxyethylenethio-5α-cholestane 4 and their corresponding 3β-chloro and 3β-acetoxy 2-3 an 5-6 analogues was carried out.The hydroxy products obtained were acetylated.The structures of the compounds obtained were established on the basis of their analytical and spectral data.Schemes 1 and 2 explain their formation.