197444-75-0

Basic information

• Product Name: H₄Ir₄(CO)4(Fe(C₅H₃P(C₆H₅)2)(C₅H₄P(C₆H₅)C₆H₄))2
• CAS NO: 197444-75-0
• Molecular Weight: 1989.7
• Mol File: 197444-75-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: H₄Ir₄(CO)4(Fe(C₅H₃P(C₆H₅)2)(C₅H₄P(C₆H₅)C₆H₄))2(CAS DataBase Reference)
• NIST Chemistry Reference: H₄Ir₄(CO)4(Fe(C₅H₃P(C₆H₅)2)(C₅H₄P(C₆H₅)C₆H₄))2(197444-75-0)
• EPA Substance Registry System: H₄Ir₄(CO)4(Fe(C₅H₃P(C₆H₅)2)(C₅H₄P(C₆H₅)C₆H₄))2(197444-75-0)

Safety Data

• Hazardous Substances Data: 197444-75-0(Hazardous Substances Data)

Upstream product

• 12150-46-8 1,1'-bis-(diphenylphosphino)ferrocene 
• 117678-68-9 dodecacarbonyltetrairidium 

Relevant articles and documents

A novel octa-substituted iridium carbonyl derivative containing the dehydrogenated dppf ligand (dppf=Fe(C5H4PPh2)2): Synthesis and crystal structure of [H4Ir4(CO)4{Fe(C5H 3PPh2)(C5H4P(Ph)C6H 4)}2]

The octa-substituted iridium carbonyl derivative [H4Ir4(CO)4{Fe(C5H 3PPh2)(C5H4P(Ph)C6H 4)}2] prepared from [Ir4(CO)12] and dppf consists of a tetrahedral Ir4 unit and two tetradentate dehydrogenated dppf ligands formed upon ortho-metallation of a cyclopentadienyl and a phenyl ring with each iridium atom coordinated by a carbonyl group, a phosphorus and an ortho-carbon of the dehydrogenated cyclopentadienyl or phenyl group.