197566-47-5Relevant articles and documents
Synthesis of trifluoro- or difluoromethylated olefins by regio- and stereocontrolled SN2′ reactions of gem-difluorinated vinyloxiranes
Ueki, Hisanori,Chiba, Takashi,Kitazume, Tomoya
, p. 3506 - 3511 (2006)
This paper presents a highly stereoselective synthesis of trifluoro- or difluoromethylated olefins via an SN2′ type fluorination or reductions of gem-difluorinated vinyloxiranes. Their fluorination with HF-Py furnished trifluoromethylated allyl
Ruthenium-catalyzed redox isomerization of trifluoromethylated allylic alcohols: Mechanistic evidence for an enantiospecific pathway
Bizet, Vincent,Pannecoucke, Xavier,Renaud, Jean-Luc,Cahard, Dominique
, p. 6467 - 6470 (2012/07/27)
Transfer news: A synthetic approach to chiral β-CF3- substituted saturated carbonyl compounds has been developed in which ruthenium complexes efficiently catalyze the redox isomerization of CF3-bearing allylic alcohols by an intramol