197715-54-1

Basic information

• Product Name: 3-Oxa-7-azabicyclo[4.1.0]heptane, 7-acetyl-4-methoxy-, [1R-(1alpha,4alpha,6alpha)]- (9CI)
• Synonyms: 3-Oxa-7-azabicyclo[4.1.0]heptane, 7-acetyl-4-methoxy-, [1R-(1alpha,4alpha,6alpha)]- (9CI)
• CAS NO: 197715-54-1
• Molecular Formula: C8H13NO3
• Molecular Weight: 171.19372
• Product Categories: ACETYLGROUP
• Mol File: 197715-54-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Oxa-7-azabicyclo[4.1.0]heptane, 7-acetyl-4-methoxy-, [1R-(1alpha,4alpha,6alpha)]- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxa-7-azabicyclo[4.1.0]heptane, 7-acetyl-4-methoxy-, [1R-(1alpha,4alpha,6alpha)]- (9CI)(197715-54-1)
• EPA Substance Registry System: 3-Oxa-7-azabicyclo[4.1.0]heptane, 7-acetyl-4-methoxy-, [1R-(1alpha,4alpha,6alpha)]- (9CI)(197715-54-1)

Safety Data

• Hazardous Substances Data: 197715-54-1(Hazardous Substances Data)

Upstream product

• 197715-50-7 (3aR,6S,7aS)-6-Methoxy-tetrahydro-[1,3,2]dioxathiolo[4,5-c]pyran 2,2-dioxide 
• 6160-56-1 methyl 2-deoxy-α-D-erythro-pentopyranoside 
• 108-24-7 acetic anhydride 
• 197715-53-0 (1R,4S,6R)-4-methoxy-3-oxa-7-azabicyclo[4.1.0]heptane 

Relevant articles and documents

Improved stereoselective synthesis of both methyl α- and β-glycosides corresponding to the amino sugar component of the E Ring of calicheamicin γ1(I) and esperamicin A1

The monosaccharide component (α and β-anomer) of the E Ring of calicheamicin γ1(I) and esperamicin A1 has been synthetized by an efficient and improved stereoselective procedure starting from methyl 2-deoxy-α- and β-D-ribopyranoside. The synthetic procedure makes use, in each case, of a cyclic sulphate and of the regioselective ring opening of an intermediate activated aziridine.