197804-92-5Relevant academic research and scientific papers
Reaction of [tris(trimethylsilyl)methyl]tribromogermane with magnesium: Generation of a bromogermylene
Ohgaki, Harunobu,Fukaya, Norihisa,Ando, Wataru
, p. 4956 - 4958 (1997)
The reaction of [tris(trimethylsilyl)methyl]tribromogermane with magnesium in the presence of olefins and acetylenes has been investigated. 1,4-Digermabicyclo[2.2.0]hexanes and bromogermacyclopent-3-ene are obtained in the reactions of [tris(trimethylsilyl)-methyl]bromogermylene with olefins and 1,3-butadiene, respectively. In the presence of diphenylacetylene a 1,2-dihydro-1,2-digermacyclobutene was formed, which can be explained in terms of an electron-transfer reaction of the bromogermylene intermediate.
