197853-42-2

Basic information

• Product Name: 1-(tert-butyldimethylsiloxy)-11(S)-hexadecanol
• Synonyms: 1-(tert-butyldimethylsiloxy)-11(S)-hexadecanol
• CAS NO: 197853-42-2
• Molecular Weight: 372.707
• Mol File: 197853-42-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(tert-butyldimethylsiloxy)-11(S)-hexadecanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(tert-butyldimethylsiloxy)-11(S)-hexadecanol(197853-42-2)
• EPA Substance Registry System: 1-(tert-butyldimethylsiloxy)-11(S)-hexadecanol(197853-42-2)

Safety Data

• Hazardous Substances Data: 197853-42-2(Hazardous Substances Data)

Upstream product

• 55362-80-6 9-bromononan-1-ol 

Downstream Products

• 197916-04-4 methyl (11S)-11-[[(4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranosyl]oxy]hexadecanoate 
• 180782-81-4 (S)-1-(hydroxycarbonyl)pentadec-10-yl O-(4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside 1,3-(B)-lactone 
• 180782-75-6 1-(methoxycarbonyl)pentadec-10(S)-yl O-(2,3-di-O-acetyl-4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside 
• 180782-78-9 1-(hydroxycarbonyl)pentadec-10(S)-yl O-(4,6-O-benzylidene-β-D-glucopyranosyl)-(1->2)-3,4-O-isopropylidene-β-D-fucopyranoside 

Relevant articles and documents

Total synthesis of tricolorin A

Tricolorin A (1), a structurally amazing resin glycoside with promising bioactivities from Ipomoea tricolor cav. (convolvulaceae), was synthesized in a total of 45 steps, with the longest linear sequence of 20 steps and overall yield of 0.65% from D-mannitol. The AB disscharide 19-membered lactone 2 was constructured by a regioselective macrolactonization using Corey-Nicolaou protocol. The macrolactone tetrasaccharide 33 was realized either by 'one- pot two-step' glycosylation procedure or by a stepwise assembly employing the 'armed-disarmed' glycosylation strategy.