197854-65-2Relevant academic research and scientific papers
Transition-metal-catalyzed immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions
Park, Jung-Woo,Jun, Chul-Ho
supporting information; experimental part, p. 7268 - 7269 (2010/08/05)
A novel and efficient grafting method for covalent bonding of functional organic molecules to silica or glass surfaces has been developed. The protocol employs transition-metal-catalyzed reactions of vinylsilanes with surface hydroxyl groups. Dimethyldivinylsilane can be used in this procedure as a linker in which one vinyl group is used for direct C-C bond formation with a functional organic molecule and the other is employed to immobilize the alkylsilyl group onto the hydroxyl surface of the solid support.
Unexpected reaction of benzoates with chlorovinylsilanes in the presence of magnesium: A facile synthesis of (3-Oxo-3-phenyl)propylvinylsilanes and further transformations
Tongco, Emily C.,Wang, Qunje,Prakash, G.K. Surya
, p. 1081 - 1084 (2007/10/03)
(3-0xo-3-phenyl)propylvinylsilanes, new functionalized monomers, have been synthesized in modest to good yields, by the reaction of methyl benzoates with chlorodimethylvinylsilane in the presence of magnesium. The synthetic potential of these new compounds was investigated in siloxane synthesis and hydroxy transformation.
