19789-33-4Relevant academic research and scientific papers
What can13C and1H NMR lithiation shifts tell us about the charge distribution in α-arylvinyllithium compounds?
Knorr, Rudolf,Lattke, Ernst,Ruhdorfer, Jakob,von Roman, Ulrich,Firl, Joachim,B?hrer, Petra
, p. 61 - 72 (2016)
The energetically stabilizing delocalization of negative electric charge from the Li[sbnd]C(α) bond into the aryl π system of α-arylvinyllithiums, Ar[sbnd]C(Li)[dbnd]CH2, is most efficient with an orthogonal relationship of the aryl ring plane
