19803-05-5

Basic information

• Product Name: 1-(4-methoxyphenyl)-2-(p-tolyloxy)ethan-1-one
• Synonyms: 1-(4-methoxyphenyl)-2-(p-tolyloxy)ethan-1-one
• CAS NO: 19803-05-5
• Molecular Weight: 256.301
• Mol File: 19803-05-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-(4-methoxyphenyl)-2-(p-tolyloxy)ethan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methoxyphenyl)-2-(p-tolyloxy)ethan-1-one(19803-05-5)
• EPA Substance Registry System: 1-(4-methoxyphenyl)-2-(p-tolyloxy)ethan-1-one(19803-05-5)

Safety Data

• Hazardous Substances Data: 19803-05-5(Hazardous Substances Data)

Upstream product

• 106-44-5 p-cresol 
• 93435-57-5 α-tosyloxy-p-methoxyacetophenone 
• 2632-13-5 2-Bromo-4'-methoxyacetophenone 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Downstream Products

• 123-11-5 4-methoxy-benzaldehyde 
• 106-44-5 p-cresol 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Relevant articles and documents

Aerobic Oxidation of Olefins and Lignin Model Compounds Using Photogenerated Phthalimide-N-oxyl Radical

A metal-free protocol to generate phthalimide-N-oxyl (PINO) radicals from N-hydroxyphthalimide (NHPI) via a photoinduced proton-coupled electron transfer process is reported. Using donor-substituted aromatic ketones, such as 4,4′-bis(diphenylamino)benzophenone (DPA-BP), PINO radicals are efficiently produced and subsequently utilized to functionalize olefins to afford a new class of alkyl hydroperoxides. The DPA-BP/NHPI/O2 photocatalytic system exhibits high efficiency toward the aerobic oxidation of β-O-4 lignin models.

Visible light induced redox neutral fragmentation of 1,2-diol derivatives

A homogeneous, redox-neutral photo fragmentation of diol derivatives was developed. Under photo/hydrogen atom transfer (HAT) dual catalysis, diol derivatives such as lignin model compounds and diol monoesters undergo selective β C(sp3)-O bond cleavage to afford ketones, phenols and acids effectively.

Hypervalent iodine in organic synthesis : Convenient and general procedures for α-functionalisation of ketones

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