198124-74-2

Upstream product

• 124-38-9 carbon dioxide 
• 198124-46-8 5-allyloxy-3-bromo-7-(tert-butyldiphenylsilyloxy)-1,4-bis(methoxymethoxy)-2,6-dimethylnaphthalene 
• 198124-45-7 5-allyloxy-3-bromo-7-(tert-butyldiphenylsilyloxy)-2,6-dimethyl-[1,4]-naphthoquinone 
• 198124-44-6 5-allyloxy-3-bromo-7-methoxymethoxy-2,6-dimethyl-[1,4]-naphthoquinone 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 85954-41-2 3-Bromo-5-hydroxy-7-methoxymethoxy-2,6-dimethyl-[1,4]naphthoquinone 
• 85954-40-1 3-Bromo-5,7-dihydroxy-2,6-dimethyl-[1,4]naphthoquinone 

Downstream Products

• 198124-77-5 C₇₂H₁₀₄O₁₉Si₂ 
• 198124-48-0 C₇₂H₁₀₂O₁₉Si₂ 
• 198124-47-9 8-allyloxy-6-(tert-butyldiphenylsilyloxy)-1,4-bis(methoxymethoxy)-3,7-dimethylnaphthalene-2-carboxylic acid β-trimethylsilylethyl ester 

Relevant academic research and scientific papers

Synthesis of highly functionalized naphthoate precursors to damavaricin D - Observation of kinetically stable benzocyclohexadienones in the bromination reactions of highly functionalized β-naphthol derivatives

Selective syntheses of the highly substituted bromonaphthoates 4a, 4b, 19, and 22 are reported. These compounds were targeted as precursors to the naphthoquinone nucleus of damavaricin D; compound 22 ultimately was used in the successful total synthesis.