198148-30-0

Basic information

• Product Name: [1-[((4-bromophenyl)imino)phenylmethyl]-1'-benzoyl]ferrocene
• CAS NO: 198148-30-0
• Molecular Weight: 548.262
• Mol File: 198148-30-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1-[((4-bromophenyl)imino)phenylmethyl]-1'-benzoyl]ferrocene(CAS DataBase Reference)
• NIST Chemistry Reference: [1-[((4-bromophenyl)imino)phenylmethyl]-1'-benzoyl]ferrocene(198148-30-0)
• EPA Substance Registry System: [1-[((4-bromophenyl)imino)phenylmethyl]-1'-benzoyl]ferrocene(198148-30-0)

Safety Data

• Hazardous Substances Data: 198148-30-0(Hazardous Substances Data)

Upstream product

• 12180-80-2 1,1’-dibenzoylferrocene 
• 106-40-1 4-bromo-aniline 

Relevant articles and documents

Cyclometallation of ferrocenylimines III. Regioselectivity in Hg(II) cyclometallated complexes

The synthesis and mercuration of a series of Schiff bases 1′-benzoyl-1-[(arylimino)phenylmethyl]ferrocene (aryl: a variety of substituted phenyls) have been studied. In all cases the mercuration occurred at the 2-position of the ferrocene ring. Oxygen → mercury coordinated products were not obtained. The X-ray crystal structure of [2-chloromercurio-1-[((phenylimino)phenylmethyl)-1′-benzoyl] ferrocene 5c has been determined; this crystallizes in the monoclinic, space group P21/c with a =10.168(3), b= 16.105(3), c = 15,463(4)A, β = 103.61(2)° and Z = 4. Refinement of atomic parameters gave an R factor of 0.038 (Rω = 0.055) for 2440 unique reflections having 1>3σ(1). The structure confirms the formation of a five-membered metallocycle on the ferrocene moiety.