19815-91-9Relevant academic research and scientific papers
Interaction of diphenyl sulfide with sulfuryl chloride
Savin,Nedel'kin
, p. 2668 - 2669 (1996)
The reaction of diphenyl sulfide with sulfuryl chloride was studied. Depending on the reaction conditions, it occurs either as chlorination of the aromatic ring or as oxidation to give sulfoxide.
TRANSMETALLATION REACTIONS INVOLVING PHENYLENEMERCURIALS
Humphries, R. E.,Al-Jabar, N. A. A.,Bowen, D.,Massey, A. G.,Deacon, G. B.
, p. 59 - 68 (2007/10/02)
When heated with Group V and Group VI elements, the phenylenemercurials (C6H4Hg)3, (C6F4Hg)3 and (C6Cl4Hg)3 form heterocycles of formulae M2(C6X4)3 and M'2(C6X4)2 where M = As, Sb, Bi and M' = S, Se, Te.The compounds Te2(C6Cl4)2 and M2(C6Cl4)3 (M = As, Sb, Bi) were also obtained by heating the elements with 1,2-I2C6Cl4, which was prepared by mercuration of 1,2-H2C6Cl4 followed by iododemercuration.Octachlorothianthrene has been obtained by heating sulphur with Te2(C6Cl4)2, C6Cl6 or C6H5I, and from the reaction between 1,2-H2C6Cl4, AlCl3, and S2Cl2.
