198221-75-9Relevant academic research and scientific papers
Chiral Proton Catalysis: A Catalytic Enantioselective Direct Aza-Henry Reaction
Nugent, Benjamin M.,Yoder, Ryan A.,Johnston, Jeffrey N.
, p. 3418 - 3419 (2004)
Despite Nature's longstanding ability to use a proton, the most prevalent Lewis acid, to both activate and orient a substrate during an enantioselective reaction, this work represents the first example of this phenomenon outside of a protein. A chiral, no
The first enantioselective and diastereoselective catalytic nitro-Mannich reaction: A new entry to chiral vicinal diamines
Yamada,Moll,Shibasaki
, p. 980 - 982 (2007/10/03)
The first example of an enantioselective and diastereoselective catalytic nitro-Mannich reaction using a second-generation heterobimetallic complex has been developed. The corresponding nitro-Mannich products were obtained in up to 83% ee with a dr up to 7:1.
