198271-81-7

Upstream product

• 333-20-0 potassium thioacyanate 
• 201738-27-4 C₃₄H₂₇ClO₉ 
• 138811-45-7 1,2,3,5,6-penta-O-benzoyl-D-galactofuranose 
• 153923-40-1 2,3,5,6-tetra-O-benzoyl-β-D-galactofuranosyl bromide 

Downstream Products

• 198271-82-8 N-(2,3,5,6-tetra-O-benzoyl-β-D-galactofuranosyl)-O-ethyl thiourethane 
• 198271-89-5 N-(2,3,5,6-tetra-O-benzoyl-β-D-galactofuranosyl)-N'-carboxyethylmethylene thiourea 
• 362594-94-3 C₃₇H₃₀N₂O₉S 
• 362594-93-2 N-(2,3,5,6-tetra-O-benzoyl-β-D-galactofuranosyl)-N'-(2,2-dimethoxyethyl) thiourea 

Relevant academic research and scientific papers

Facile synthesis of glycofuranosyl isothiocyanates

Peracylated glycofuranosyl isothiocyanates are obtained under smooth conditions starting from the corresponding glycosyl chloride by reaction with potassium thiocyanate in anhydrous acetone at room temperature, classical conditions for the synthesis of gl

Reactions of per-O-benzoyl-β-D-galf isothiocyanate, a chiral resolving agent

Tetra-O-benzoyl-β-D-galactofuranosyl isothiocyanate (1) was readily prepared (90% yield) from per-O-benzoyl-D-galactofuranose, via the glycosyl bromide. Reaction of 1 with alcohols, amines and amino acids afforded a variety of glycosylthiourethanes and glycosylthioureides. The isothiocyanate 1 showed to be useful as a chiral resolving agent. The resolution of recemic primary and secondary mines and aminoalcohols was readily accomplished, in analytical and preparative scale, by condensation of such compounds with 1.