198547-55-6Relevant academic research and scientific papers
Generation and intramolecular cyclization of difluoroalkyl radicals via single electron transfer from the benzeneselenolate anion: Synthesis of α,α-difluoro-γ-lactams
Uneyama, Kenji,Yanagiguchi, Takeo,Asai, Hideki
, p. 7763 - 7764 (1997)
Several α,α-difluoro-γ-lactams (2) were prepared by radical cyclization of amides (1) which were initiated by a single transfer(SET) process from the benzenesclenolate anion. Deselenation of these lactams (2) gave the corresponding α,α-difluoro-β-exomethylene lactams (8).
