19904-92-8

Upstream product

• 20264-95-3 2-(4-nitrophenyl)ethyl chloride 
• 104-94-9 4-methoxy-aniline 
• 6948-72-7 4-[2-p-toluenesulphonyloxy ethyl]nitrobenzene 
• 41049-91-6 2-(p-nitrophenyl)ethyl p-nitrobenzenesulphonate 
• 100-13-0 4-nitrostyrene 
• 115951-29-6 2-(p-nitrophenyl)ethyl p-chlorobenzenesulphonate 
• 115951-31-0 2-(p-nitrophenyl)ethyl benzenesulphonate 

Downstream Products

• 210585-28-7 N-(4-Methoxy-phenyl)-N-[2-(4-nitro-phenyl)-ethyl]-malonamic acid 
• 210585-70-9 1-(4-Methoxy-phenyl)-4-(4-nitro-phenyl)-2-oxo-pyrrolidine-3-carboxylic acid (1R,2S,3S,4R)-4,7,7-trimethyl-3-naphthalen-1-yl-bicyclo[2.2.1]hept-2-yl ester 
• 174618-62-3 2-Diazo-N-(4-methoxy-phenyl)-N-[2-(4-nitro-phenyl)-ethyl]-malonamic acid (1R,2S,3S,4R)-4,7,7-trimethyl-3-naphthalen-1-yl-bicyclo[2.2.1]hept-2-yl ester 

Relevant academic research and scientific papers

Copper-Catalyzed Intermolecular Hydroamination of Arylamines or Aza-Heterocycles with Nitrostyrene Derivatives

A new copper-catalyzed protocol for the intermolecular anti-Markovnikov addition of arylamines or heterocycles to terminal and unsymmetrical 1,2-disubstituted vinylarenes has been developed. The direct hydroamination is catalyzed by a readily available N-

Kinetics and Mechanism of Reactions between 2-Phenylethyl Benzenesulphonates and Anilines in Methanol

Kinetics of reactions between 2-phenylethyl benzenesulphonates and anilines in methanol at 65.0 deg C have been studied; the mechanism is discussed on the basis of cross interaction constants, ρij.The overall reaction was found to proceed by a dissociative SN2 mechanism with a relatively small degree of aryl participation.The fraction of the phenonium ion intermediate captured by the nucleophile, aniline, in the aryl-assisted pathway has been shown to increase with a stronger nucleophile, and a four-centre transition state in an intermolecular SNi mechanism is suggested for the aryl-unassisted pathway.