199117-21-0Relevant articles and documents
Intramolecular electron transfer in mixed-valence biferrocenium salts containing heteroatoms: Preparation, structure, and 57Fe m?ssbauer characteristics
Dong, Teng-Yuan,Chang, Chung-Kay,Lee, Shu-Hwei,Lai, Long-Li,Chiang, Michael Yen-Nan,Lin, Kuan-Jiuh
, p. 5816 - 5825 (1997)
A convenient new method is developed for the preparation of 1′,1?-disubstituted biferrocenes which can be oxidized with iodine to a new series of mixed-valence compounds. The X-ray structures of 1′,1?-dimethoxymethyl, 1′,1?-diethoxyl, 1′,1?-dimethyl, 1′,1?-dihydroxymethyl, 1′,1?-dibenzoyloxymethyl, 1′,1?-dimethylthio, and 1′,1?-diethylthio neutral biferrocenes and the mixed-valence 1′,1?-diethoxyl, 1′,1?-dimethyl, 1′,1?-dibenzoyloxymethyl, and 1′,1?-diphenylthio biferrocenium triiodide salts have been determined at 298 K. The rates of intramolecular electron transfer in these mixed-valence cations were estimated by variable-temperature 57Fe M?ssbauer experiment.