199277-46-8Relevant academic research and scientific papers
Dendritic Styryl TADDOLs as Novel Polymer Cross-Linkers: First Application in an Enantioselective Et2Zn Addition Mediated by a Polymer-Incorporated Titanate
Rheiner, P. Beat,Sellner, Holger,Seebach, Dieter
, p. 2027 - 2032 (1997)
TADDOLs (αααα-tetraaryl-1,3-dioxolane-4,5- dimethanols) with dendritic branches attached to the aryl groups and with 8 or 16 peripheral styryl double bonds have been synthesized (4 and 5). With these compounds, dendritic molecules were employed for the fi
Dendritic TADDOLs: Synthesis, characterization and use in the catalytic enantioselective addition of Et2Zn to benzaldehyde
Rheiner, P. Beat,Seebach, Dieter
, p. 3221 - 3236 (2007/10/03)
The versatile chiral ligand for polar metal centers, TADDOL ((R,R)-a,a,a′,a′-tetraaryl-1,3-dioxolane-4,5-dimethanol), has been incorporated as core building block into dendrimers by way of benzylation of a fourfold phenolic derivative (hexol 2) with Frech
